- 【SCI4区通讯作者宋晓锋】Synthesized polyurethane from p-toluenesulfonyl isocyanate and epichlorohydrin via salen catalysis
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- 所属单位：化学工程学院
- 发表刊物：Polymers for Advanced Technologies
- 项目来源：其他课题
- 摘要：Polyurethane (PU) as a multifunctional material has been produced by various methods. In this work, a series of novel chloric PUs are made from p-toluene sulfonyl isocyanate (TSI) and epichlorohydrin (ECH) via direct salen catalysis under mild temperature. Catalytic efficiency and activity of salen metal complexes are analyzed and evaluated. The salen-cobalt (III) (DNP) exhibits high yield, excellent urethane selectivity, narrow polymer weight distribution in bulk polymerization with the molar ratio of TSI with catalyst changing. And compared to bulk polymerization, salen-cobalt (III) (DNP) can promote the reaction better in solution polymerization and synthesize the product with higher molecular weight. The obtained polymer shows excellent thermal stability, and its thermal degradation starts from 240.8C. So, it will provide experience for developing functional PU under mild reaction conditions.
- 合写作者：陈兴,宋晓峰
- 第一作者：宋晓峰
- 论文类型：期刊论文
- 卷号：33
- 页面范围：1
- 是否译文：否
- 发表时间：2022-01-01
