所属单位:化学与生命科学学院
教研室:化学教研室
发表刊物:Journal of Solid State Chemistry
项目来源:自选课题
关键字:Hydrothermal synthesis
摘要:Two newhybridcompoundsbasedonKeggin-typepolyoxometalates:{[PMo12O40][Ni(Phen)2
(H2O)]2} K 2OH (1) and[Cd2(Phen)4Cl2][HPW12O40] H2O (2) (Phen¼1,10-phenanthroline),havebeen
preparedandcharacterizedbyIR,UV–vis,XPS,XRDandsinglecrystalX-raydiffractionanalyses.Compound
1 exhibitsa1-DchainstructureconstructedfromPseudo-Kegginpolyoxometalatebi-supportedtransition
metalcoordinationcomplexeslinkedbyK+ ions.Compound 2 containsPseudo-Kegginpolyoxoanions
[HPW12O40]2 andnovelmetal–chloride–ligandcoordinationcomplexes[Cd2(Phen)4Cl2]2+.
第一作者:王严
论文类型:期刊论文
卷号:184
页面范围:1
是否译文:否
发表时间:2011-01-15