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Affiliation of Author(s):化学与生命科学学院
Teaching and Research Group:化学教研室
Journal:Journal of Solid State Chemistry
Funded by:自选课题
Key Words:Hydrothermal synthesis
Abstract:Two newhybridcompoundsbasedonKeggin-typepolyoxometalates:{[PMo12O40][Ni(Phen)2 (H2O)]2} K 2OH (1) and[Cd2(Phen)4Cl2][HPW12O40] H2O (2) (Phen¼1,10-phenanthroline),havebeen preparedandcharacterizedbyIR,UV–vis,XPS,XRDandsinglecrystalX-raydiffractionanalyses.Compound 1 exhibitsa1-DchainstructureconstructedfromPseudo-Kegginpolyoxometalatebi-supportedtransition metalcoordinationcomplexeslinkedbyK+ ions.Compound 2 containsPseudo-Kegginpolyoxoanions [HPW12O40]2 andnovelmetal–chloride–ligandcoordinationcomplexes[Cd2(Phen)4Cl2]2+.
First Author:Wang Yan
Indexed by:Journal paper
Volume:184
Page Number:1
Translation or Not:no
Date of Publication:2011-01-15