所属单位：化学工程学院
教研室：化学工程学院
发表刊物：J. Mol. Struct.
项目来源：自选课题
关键字：Calixarenes；cobalt；4,4’-Bipyridyl；Metal-organic aggregates；Solvothermal synthesis
摘要：Two novel calixarene-based compounds, {[Co4Cl(TC4A)(HCOO)3]2(4,40-bpy)2} (CIAC-206) and {[Co3(H2O)(SC4A-SO2)(HCOO)2]2(4,40-bpy)}n (CIAC-207) (H4TC4A = p-tert-butylthiacalix[4]arene, SC4A-SO2 = p-tert-butylsulfonylcalix[4]arene, 4,40-bpy = 4,40-bipyridyl) were synthesized under solvothermal conditions, and characterized by single crystal X-ray diffraction analysis, TG–DSC analysis, elemental analysis and IR spectroscopy. These two structures are featured with isolated Z-shaped Co8 entities containing two Co4-TC4A subunits bridged by two parallel 4,40-bpy (CIAC-206) and some zigzag chains with [Co3-SC4A-SO2]2 dimers bridged by single 4,40-bpy (CIAC-207), respectively. In order to evaluate their properties, the N2 sorption behavior and magnetic property were examined.
合写作者：刘伟,刘梅,杜尚超,廖五平,李亚丰
第一作者：李亚丰
论文类型：期刊论文
卷号：1060
页面范围：1
字数：1
ISSN号：0022-2860
是否译文：否
发表时间：2014-02-28