所属单位：化学工程学院
教研室：化学工程学院
发表刊物：Acta Crystallographica Section E
项目来源：自选课题
关键字：crystal,x-ray single-crystal diffraction
摘要：A new organically templated open-framework cerium sulfate, {(C4H16N3)[Ce(SO4)3(H2O)]}n, was hydrothermally synthesized. The CeIII cation is nine-coordinated by nine O atoms, including one water molecule. Two of the SO4 groups afford one monodentate and bidentate linkages as the bridge to connect adjacent CeIII cations, while the third SO4 group attaches the CeIII cation in a bidentate mode. The crystal structure consists of layers composed of eight-membered-ring networks formed by four CeO9 polyhedra and four SO4 tetrahedra. The triply protonated diethylenetriamine cations are located between adjacent layers and connect the layers via hydrogen bonds.
第一作者：李亚丰
论文类型：期刊论文
卷号：66
期号：9
页面范围：1
ISSN号：1600-5368
是否译文：否
发表时间：2010-09-21