Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Hits:
Affiliation of Author(s):化学工程学院
Teaching and Research Group:化学工程学院
Journal:J. Mol. Struct.
Funded by:自选课题
Key Words:Calixarenes；cobalt；4,4’-Bipyridyl；Metal-organic aggregates；Solvothermal synthesis
Abstract:Two novel calixarene-based compounds, {[Co4Cl(TC4A)(HCOO)3]2(4,40-bpy)2} (CIAC-206) and {[Co3(H2O)(SC4A-SO2)(HCOO)2]2(4,40-bpy)}n (CIAC-207) (H4TC4A = p-tert-butylthiacalix[4]arene, SC4A-SO2 = p-tert-butylsulfonylcalix[4]arene, 4,40-bpy = 4,40-bipyridyl) were synthesized under solvothermal conditions, and characterized by single crystal X-ray diffraction analysis, TG–DSC analysis, elemental analysis and IR spectroscopy. These two structures are featured with isolated Z-shaped Co8 entities containing two Co4-TC4A subunits bridged by two parallel 4,40-bpy (CIAC-206) and some zigzag chains with [Co3-SC4A-SO2]2 dimers bridged by single 4,40-bpy (CIAC-207), respectively. In order to evaluate their properties, the N2 sorption behavior and magnetic property were examined.
Co-author:刘伟,刘梅,杜尚超,廖五平,李亚丰
First Author:Yafeng Li
Indexed by:Journal paper
Volume:1060
Page Number:1
Number of Words:1
ISSN No.:0022-2860
Translation or Not:no
Date of Publication:2014-02-28
