所属单位：化学工程学院

教研室：化工原理

发表刊物：Journal of Alloys and Compounds

项目来源：其他课题

关键字：Sulfur Disordered mesoporous polyacenes/sulfur

摘要：In this work, disordered mesoporous polyacenes/sulfur (DM-PAs/S) composites with the S content of 50-80 wt % were prepared via a simple melt-diffusion strategy. In order to obtain such DM-PAs/S composites, the non-sulfur-containing disordered mesoporous polyacenes (DM-PAs) precursor, which had a high BET surface area of 1136.0 m 2 /g, a pore volume of 1.37 cm 3 /g and unique bimodal mesopores (2.98/7.39 nm), was firstly prepared by using phenol-formaldehyde (PF) resin as raw material as well as both polyethylene glycol (PEG) and ZnCl 2 as activation agents. Electrochemical tests demonstrated that, the as-prepared DM-PAs/S could be served as superior cathode materials for lithium-sulfur batteries. It was disclosed that the DM-PAs/S with the S content of about 67 wt % (S-DM-PAs/S-67) presented the best electrochemical properties when the specific capacity is calculated based on the total mass of DM-PAs/S composite containing active sulfur and inactive DM-PAs. At a charge/discharge rate of 1 C, the S-DM-PAs/S-67 electrode exhibits a good long-term cycling stability with a high reversible capacity of about513.57 mAh/g Sulfur after 500 cycles. The advanced electrochemical performances should be attributed to the uniform distribution of sulfur in the DM-PAs matrix, high electronic conductivity of DM-PAs, and the effective hinder of dissolvable polysulfides by the pores in the DM-PAs.

合写作者：赵焕萍,王佳伟,姚岑

第一作者：李伟

论文类型：期刊论文

页面范围：2

字数：3

是否译文：否

发表时间：2017-02-05