Light-scattering and luminophores enrichment enhanced electro- chemiluminescence by 2D porous Ru@SiO2 nanoparticle membrane and its application in ultrasensitive detection of prostate specific antigen. Light-scattering and luminophores enrichment enhanced electro- chemiluminescence by 2D porous Ru@SiO2 nanoparticle membrane and its application in ultrasensitive detection of prostate specific antigen.