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所属单位：化学与生命科学学院

教研室：化学教研室

发表刊物：ACS Nano

项目来源：自选课题

摘要：Biomaterials in nature often exhibit hierarchical chiral structures with an intriguing mechanism involving hierarchical chirality transfer from molecular to supramolecular and the nano- or microscale level. To mimic the cross-level chirality transfer, we present here one kind of host−guest complex system built of β-cyclodextrin (β-CD), sodium dodecyl sulfate (SDS), and fluorescent dyes, which show multilevel chirality, including molecular chirality of β-CD, induced supramolecular chirality of β-CD/SDS host−guest complexes, a chiral lattice selfassembled nanosheet, mesoscopic chirality of an assembled helical tube, induced chirality of a dye-doped chiral tube. The hierarchical chirality involved a chiral lattice self-assembly process, which can be identified by small-angle X-ray scattering, optical studies, circular dichroism, and circularly polarized luminescence spectral measurements. Benefiting from the chiral lattice self-assembly, intense circularly polarized luminescence was observed from the achiral dye-doped complexes with a large dissymmetry factor up to +0.1. This work thus provides a feasible insight for developing hierarchical chiroptical materials based on the lattice self-assembly

合写作者：秦绪金,高晓慧,马凯,朱雪峰,金雪,蒋凌翔,段鹏飞

第一作者：郭佩佩

论文类型：期刊论文

页面范围：1

是否译文：否

发表时间：2020-03-04