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所属单位：化学与生命科学学院

教研室：化学教研室

发表刊物：Chinese Chemical Letters

项目来源：省、市、自治区科技项目

摘要：Photon upconversion (UC) based on triplet-triplet annihilation (TTA) in quasi-solid or solid state has been attracting much research interest due to its great potential applications. To get effective UC, precisely controlled donor-acceptor interaction is vitally important. Chiral self-assembly provides a powerful approach for sophisticated regulation of molecular interaction. Here we report a chiral self-assembly controlled TTA-UC system composed of chiral acceptor and achiral donor. It is found that racemic mixture of acceptors could form straight fibrous nanostructures, which show strong UC emission, while chiral assemblies for homochiral acceptors emit weak upconverted light. The racemic assemblies allow efficient triplet-triplet energy transfer (TTET) and further realize efficient UC emission, while the homochiral assemblies from chiral acceptor produce twisted nanostructures, suppressing efficient triplet energy transfer and annihilation. The establishment of such chiral self-assembly controlled UC system highlights the potential applications of triplet fusion in optoelectronic materials and provides a new perspective for designing highly effective UC systems.

合写作者：秦绪金,韩建雷,杨东,陈文杰,赵佟翰,金雪,段鹏飞

第一作者：郭佩佩

论文类型：期刊论文

页面范围：2

是否译文：否

发表时间：2019-04-17